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Biotin-cGMP and -cAMP are able to permeate through the gap ..:
Chunxu Yuan ; Luca Gerhards ; Ilia A. Solov'yov.
https://www.frontiersin.org/articles/10.3389/fopht.2023.1334602/full. , 2024
https://www.frontiersin.org/articles/10.3389/fopht.2023.1334602/full. , 2024