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1 Ergebnisse
1
Methide Affinity Scale: Key Thermodynamic Data Underpinning..:
Weam A. O. Altalhi
;
Bun Chan
;
Richard A. J. O'Hair
doi:10.1021/acs.jpca.3c05974.s001. , 1753
Link:
https://doi.org/10.1021/acs.jpca.3c05974.s001
RT Journal T1
Methide Affinity Scale: Key Thermodynamic Data Underpinning Catalysis, Organic Synthesis, and Organometallic and Polymer Chemistry
UL https://suche.suub.uni-bremen.de/peid=base-ftdeakinunifig:oai:figshare.com:article_25120026&Exemplar=1&LAN=DE A1 Weam A. O. Altalhi A1 Bun Chan A1 Richard A. J. O'Hair YR 1753 K1 Biophysics K1 Biochemistry K1 Evolutionary Biology K1 Ecology K1 Developmental Biology K1 Infectious Diseases K1 Computational Biology K1 Chemical Sciences not elsewhere classified K1 Physical Sciences not elsewhere classified K1 vertical detachment energies K1 singlet cation f K1 key thermodynamic quantity K1 5 </ sub K1 sup >–</ sup K1 sup >+</ sup K1 2 –</ sup K1 methide affinity scale K1 group 17 ) K1 cases decrease going K1 3 </ sub K1 modest increase moving K1 4 </ sub K1 mez → z K1 moving across K1 group 3 K1 group 2 K1 dianion mez K1 increase across K1 group 4 K1 4 kj K1 mas increase K1 − 820 K1 → x K1 tzvp calculations K1 transmetalation steps K1 tetramethylborate anion K1 poorly developed K1 permethyl species K1 organic synthesis K1 methide affinities K1 many areas K1 kinetic stability K1 group 1 K1 grignard reaction K1 gas phase K1 g K1 energy changes K1 electron loss K1 dianion cf K1 clearest trends JF doi:10.1021/acs.jpca.3c05974.s001 LK http://dx.doi.org/https://doi.org/10.1021/acs.jpca.3c05974.s001 DO https://doi.org/10.1021/acs.jpca.3c05974.s001 SF ELIB - SuUB Bremen
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