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The mechanism of action of Cu2+ on the frog skin:

Ferreira, Karin T.G. ; Guerreiro, Maria M. ; Svensson, Wivi M.
Biochimica et Biophysica Acta (BBA) - Biomembranes.  552 (1979)  2 - p. 341-345 , 1979
Link: https://doi.org/10.1016/0005-2736(79)90288-8