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The discrete-ion effect in ionic double-layer theory:

Levine, S. ; Mingins, J. ; Bell, G.M.
Journal of Electroanalytical Chemistry and Interfacial Electrochemistry.  13 (1967)  3 - p. 280-329 , 1967
Link: https://doi.org/10.1016/0022-0728(67)80125-6