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The negative ion mass spectra of deprotonated 2,5-diketopip..:

Wabnitz, Paul A. ; Waugh, Russell J. ; Eckersley, Mark A....
International Journal of Mass Spectrometry and Ion Processes.  154 (1996)  3 - p. 193-201 , 1996
Link: https://doi.org/10.1016/0168-1176(96)04378-9