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Evidence for a collagen-like protein within spicules of coe..:

Silberberg, Martin S. ; Ciereszko, Leon S. ; Jacobson, Ralph A..
Comparative Biochemistry and Physiology Part B: Comparative Biochemistry.  43 (1972)  2 - p. 323-332 , 1972
Link: https://doi.org/10.1016/0305-0491(72)90291-x