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The discovery of long acting β2-adrenoreceptor agonists:

Brown, Alan D. ; Bunnage, Mark E. ; Glossop, Paul A....
Bioorganic & Medicinal Chemistry Letters.  17 (2007)  14 - p. 4012-4015 , 2007
Link: https://doi.org/10.1016/j.bmcl.2007.04.081