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Chemical analysis of obsidian by a SIMS/EDX combined system:

Kudriavtsev, Yuriy ; Gallardo, Salvador ; Avendaño, Miguel...
Nuclear Instruments and Methods in Physics Research Section B: Beam Interactions with Materials and Atoms.  343 (2015)  - p. 153-157 , 2015
Link: https://doi.org/10.1016/j.nimb.2014.11.029