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Geant4 X-ray fluorescence with updated libraries:

Bakr, Samer ; Cohen, David D. ; Siegele, Rainer...
Nuclear Instruments and Methods in Physics Research Section B: Beam Interactions with Materials and Atoms.  507 (2021)  - p. 11-19 , 2021
Link: https://doi.org/10.1016/j.nimb.2021.09.009