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Tm3+:CaF2 for 1.9 μm laser operation:

Camy, P. ; Doualan, J.L. ; Renard, S....
Optics Communications.  236 (2004)  4-6 - p. 395-402 , 2004
Link: https://doi.org/10.1016/j.optcom.2004.03.055