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Definitive confirmation for through-space bond dominance in..:

Mackenzie-Ross, H. ; Brunger, M.J. ; Wang, F....
Journal of Electron Spectroscopy and Related Phenomena.  123 (2002)  2-3 - p. 389-395 , 2002
Link: https://doi.org/10.1016/s0368-2048(02)00035-x