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Ratcheting of the substrate from the zymogen to proteinase ..:

Bianchini, Elsa P. ; Orcutt, Steven J. ; Panizzi, Peter..
Proceedings of the National Academy of Sciences.  102 (2005)  29 - p. 10099-10104 , 2005
Link: https://doi.org/10.1073/pnas.0504704102