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Solute diffusion is hindered in the mitochondrial matrix:

Dieteren, Cindy E. J. ; Gielen, Stan C. A. M. ; Nijtmans, Leo G. J....
Proceedings of the National Academy of Sciences.  108 (2011)  21 - p. 8657-8662 , 2011
Link: https://doi.org/10.1073/pnas.1017581108