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A search for methane in the atmosphere of GJ 1214b via GTC ..:

Wilson, P. A. ; Colón, K. D. ; Sing, D. K....
Monthly Notices of the Royal Astronomical Society.  438 (2014)  3 - p. 2395-2405 , 2014
Link: https://doi.org/10.1093/mnras/stt2356