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Observation of C$_8$H$^-$ toward IRC +10216:

Kentarou, Kawaguchi ; Fujimori, Ryuji ; Aimi, Sayaka...
Publications of the Astronomical Society of Japan.  59 (2007)  5 - p. L47-L50 , 2007
Link: https://doi.org/10.1093/pasj/59.5.l47