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Nocturnal melatonin onset is phase locked to the primary sl..:

Shochat, T. ; Luboshitzky, R. ; Lavie, P.
American Journal of Physiology-Regulatory, Integrative and Comparative Physiology.  273 (1997)  1 - p. R364-R370 , 1997
Link: https://doi.org/10.1152/ajpregu.1997.273.1.r364